[Ebook.ZjlD] Copper-Catalyzed Asymmetric Synthesis
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Book Details :
Published on: 2014-03-31
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Original language: English
This book reflects the increasing interest among the chemical synthetic community in the area of asymmetric copper-catalyzed reactions, and introduces readers to the latest, most significant developments in the field. The contents are organized according to reaction type and cover mechanistic and spectroscopic aspects as well as applications in the synthesis of natural products. A whole chapter is devoted to understanding how primary organometallics interact with copper to provide selective catalysts for allylic substitution and conjugate addition, both of which are treated in separate chapters. Another is devoted to the variety of substrates and experimental protocols, while an entire chapter covers the use on non-carbon nucleophiles. Other chapters deal with less-known reactions, such as carbometallation or the additions to imines and related systems, while the more established reactions cyclopropanation and aziridination as well as the use of copper (II) Lewis acids are warranted their own special chapters. Two further chapters concern the processes involved, as determined by mechanistic studies. Finally, a whole chapter is devoted to the synthetic applications. This is essential reading for researchers at academic institutions and professionals at pharmaceutical or agrochemical companies. Alkene - Wikipedia In organic chemistry an alkene is an unsaturated hydrocarbon that contains at least one carboncarbon double bond. The words alkene olefin and olefine are used ... Abstracts of Articles on Organic Synthesis New Abstracts. Abstracts of articles in the field of organic synthesis published in the most highly regarded organic chemistry journals. Pd-Catalyzed Isocyanide ... Nature Communications - Nature Publishing Group As shown above CO 2 has multiple reactive sites: the carbon atom is an electrophilic Lewis acid centre and the oxygen atoms act as weak nucleophilic Lewis base. doi: 10.1021/cr9500038 - ACS Publications Home Page 12-Amino Alcohols and Their Heterocyclic Derivatives as Chiral Auxiliaries in Asymmetric Synthesis Advanced Synthesis & Catalysis - Early View - Wiley Online ... Iridium-Catalyzed Asymmetric Hydrogenation of Tosylamido-Substituted Pyrazines for Constructing Chiral Tetrahydropyrazines with an Amidine Skelton European Journal of Organic Chemistry - Early View - Wiley ... One-pot magic: A green organocatalytic one-pot procedure for the dihydroxylation of alkenes is described. The reaction proceeds through an intermolecular ring opening ... Ullmann Reaction - Organic Chemistry Portal Ullmann Reaction. There are two different transformations referred as the Ullmann Reaction. The "classic" Ullmann Reaction is the synthesis of symmetric biaryls via ... Dynamic kinetic resolution in asymmetric synthesis - Wikipedia Applications Noyori Asymmetric Hydrogenation. One of the more classic applications of DKR is Noyoris asymmetric hydrogenation. The presence of an acidic center ... Tetrahedron: Asymmetry - ScienceDirect.com The online version of Tetrahedron: Asymmetry at ScienceDirect.com the world's leading platform for high quality peer-reviewed full-text journals. Copper-Catalyzed CH Functionalization Reactions ... Shanghai Center for Systems Biomedicine Ministry of Education Key Laboratory of Systems Biomedicine Shanghai Jiao Tong University 800 Dongchuan Road Shanghai ...
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